Macropolyhedral boron-containing cluster chemistry: isolation and characterization of twenty-one-vertex [(PMe2Ph)3HReB20H15Ph(PHMe2)]

dc.contributor.author	Kaur, Pervinder
dc.contributor.author	Perera, Sarath D.
dc.contributor.author	Jelinek, T.
dc.contributor.author	Štíbr, Bohumil
dc.contributor.author	Kennedy, John D.
dc.contributor.author	Clegg, William
dc.contributor.author	Thornton-Pett, Mark
dc.date.accessioned	2019-05-31T04:08:53Z
dc.date.available	2019-05-31T04:08:53Z
dc.date.issued	1997
dc.identifier.uri	http://repository.ou.ac.lk/handle/94ousl/102
dc.description.abstract	Reaction of B20H16 with [ReH5(PMe2Ph)3]yields the twenty-one-vertex metallaborane [(PMe2Ph)3HReB20H15Ph-(PHMe2)] which consists of a closo twelve-vertex {B12} unit and a nido eleven-vertex {B11} unit fused with a common triangular face, with the {(PMe2Ph)3HRe} moiety capping exo to the nido {B11} unit with three Re–H–B bonds; an unusual reductive P-phenyl cleavage of a PMe2Ph moiety to give B-pendant exo PHMe2 and exo Ph moieties on the open face of the eleven-vertex subcluster is also apparent.	en_US
dc.language.iso	en_US	en_US
dc.subject	cluster chemistry	en_US
dc.subject	macropolyhedra	en_US
dc.title	Macropolyhedral boron-containing cluster chemistry: isolation and characterization of twenty-one-vertex [(PMe2Ph)3HReB20H15Ph(PHMe2)]	en_US
dc.type	Article	en_US