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Macropolyhedral boron-containing cluster chemistry. Ligandinduced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex [(ƞ5 -C5Me5)HIrB18 H19(PMe2Ph)] and the related carbene complex [(ƞ5-C5Me5)HIrB18H19 {C(NHMe)2}]

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