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3- Diphenylphosphino-(I R)-( +)=camphor Dimethyl hydrazone and its Complexes with Group 6 Metal Carbonyls: Crystal Structures of the Hydrazone and [Mo(CO)4(PPh2C10H15NNMe2)]

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dc.contributor.author Perera, Sarath D.
dc.contributor.author Shaw, Bernard L.
dc.contributor.author Thornton-Pett, Mark
dc.date.accessioned 2019-05-30T11:08:50Z
dc.date.available 2019-05-30T11:08:50Z
dc.date.issued 1991
dc.identifier.uri http://repository.ou.ac.lk/handle/94ousl/89
dc.description.abstract Prolonged treatment of (1R)-(+)-camphor with 1,l -dimethylhydrazine gives (1R)-( +)-camphor dimethylhydrazone 3a which with LiBu, followed by PPh,CI, gives the corresponding compound 3c which has the Ph2P group in 3-exo position and the C=N-NMe, group in the Z configuration. This new phosphine was quaternized with Mel to give a phosphonium salt and converted into the corresponding sulphide and oxide. en_US
dc.language.iso en_US en_US
dc.subject Dimethyl hydrazone en_US
dc.title 3- Diphenylphosphino-(I R)-( +)=camphor Dimethyl hydrazone and its Complexes with Group 6 Metal Carbonyls: Crystal Structures of the Hydrazone and [Mo(CO)4(PPh2C10H15NNMe2)] en_US
dc.type Article en_US


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