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A new method of creating co-ordinative unsaturation: synthesis and reactions of a reactive iridium(I) complex [Ir(CO){PPh2CH2C(But)=N-N=C(But)CH2PPh2}]PF6: crystal structures of [Ir(CO)(ŋ2-L){PPh2CH2-C(But)=N-N=C(But)CH2PPh2}]PF6 (L = MeO2CC=CCO2Me or COCH=CHCONMe)

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